3d transition metal doping of semiconducting boron carbides

نویسندگان

  • Peter A. Dowben
  • Orhan Kizilkaya
  • Jing Liu
  • B. Montag
  • K. Nelson
  • Jennifer I. Brand
چکیده

The introduction metallocenes, in particular ferrocene (Fe(η-C5H5)2), cobaltocene (Co(η-C5H5)2), and nickelocene (Ni(η-C5H5)2), together with the carborane source molecule closo-1,2-dicarbadodecaborane, during plasma enhanced chemical vapor deposition, will result in the transition metal doping of semiconducting boron carbides. Here we report using ferrocene to introduce Fe dopants, and a semiconducting boron-carbide homojunction has been fabricated. The diode characteristics are very similar to those fabricated with Co and Ni doping.

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تاریخ انتشار 2017